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Ionic reactions in two dimensions with disorder

  • University of California at Los Angeles

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

We analyze the dynamics of the ion-dipole pairing reaction in the two-dimensional Coulomb gas in the presence of disorder. Sufficiently singular disorder forces the critical temperature of the Kosterlitz-Thouless-Berezinskii fixed point to be nonuniversal. This disorder leads to anomalous ion pairing kinetics with a continuously variable decay exponent. Sufficiently strong disorder eliminates the transition altogether. For ions that are chemically reactive, anomalous kinetics with a continuously variable decay exponent also occurs in the high-temperature regime. The Coulomb interaction inhibits reactant segregation, and so the ionic [Formula Presented] reaction behaves like the nonionic [Formula Presented] reaction.

Original languageEnglish
Pages (from-to)1487-1493
Number of pages7
JournalPhysical Review E
Volume58
Issue number2
DOIs
StatePublished - 1998

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