Quinoline-substituted zinc(II) phthalocyanine for the dual detection of ferric and zinc ions

Ankush Gupta; A. Rong Kim; Kyung Sub Kim; Kun Na; Myung Seok Choi; Jong S. Park

doi:10.1002/bkcs.10402

Quinoline-substituted zinc(II) phthalocyanine for the dual detection of ferric and zinc ions

Ankush Gupta
, A. Rong Kim
, Kyung Sub Kim
, Kun Na
, Myung Seok Choi
, Jong S. Park

Department of Applied Sciences, Lyallpur Khalsa College of Engineering
Dong-A University
Konkuk University
Pusan National University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Here we present the synthesis and properties of quinoline-substituted zinc(II) phthalocyanine, Zn[Pc(O-QN)₄]. Zn[Pc(O-QN)₄] can function as a highly selective chemosensor against Fe³⁺ and Zn²⁺ ions, exhibiting efficient fluorescence quenching and enhancement, respectively. Various characterization techniques were employed to investigate the intermolecular interactions of Zn[Pc(O-QN)₄] with metal ions. A double-electron exchange and a forbidden photoinduced electron transfer behavior in Zn[Pc(O-QN)₄] were attributed to such opposite responses. Furthermore, by taking advantage of selectivity, we successfully employed Zn[Pc(O-QN)₄] to stain and record confocal fluorescence microscopy images of Chang liver cells in the presence of metal ions.

Original language	English
Pages (from-to)	2179-2184
Number of pages	6
Journal	Bulletin of the Korean Chemical Society
Volume	36
Issue number	9
DOIs	https://doi.org/10.1002/bkcs.10402
State	Published - 1 Sep 2015

Bibliographical note

Publisher Copyright:
© 2015 Korean Chemical Society & Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

Dual detection
Fluorescence quenching
Phthalocyanine
Quinolone-substituted
Stern-Volmer constant

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10.1002/bkcs.10402

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@article{509da0cb719f43e89ff4d78a87a13fe1,

title = "Quinoline-substituted zinc(II) phthalocyanine for the dual detection of ferric and zinc ions",

abstract = "Here we present the synthesis and properties of quinoline-substituted zinc(II) phthalocyanine, Zn[Pc(O-QN)4]. Zn[Pc(O-QN)4] can function as a highly selective chemosensor against Fe3+ and Zn2+ ions, exhibiting efficient fluorescence quenching and enhancement, respectively. Various characterization techniques were employed to investigate the intermolecular interactions of Zn[Pc(O-QN)4] with metal ions. A double-electron exchange and a forbidden photoinduced electron transfer behavior in Zn[Pc(O-QN)4] were attributed to such opposite responses. Furthermore, by taking advantage of selectivity, we successfully employed Zn[Pc(O-QN)4] to stain and record confocal fluorescence microscopy images of Chang liver cells in the presence of metal ions.",

keywords = "Dual detection, Fluorescence quenching, Phthalocyanine, Quinolone-substituted, Stern-Volmer constant",

author = "Ankush Gupta and Kim, \{A. Rong\} and Kim, \{Kyung Sub\} and Kun Na and Choi, \{Myung Seok\} and Park, \{Jong S.\}",

note = "Publisher Copyright: {\textcopyright} 2015 Korean Chemical Society \& Wiley-VCH Verlag GmbH \& Co. KGaA.",

year = "2015",

month = sep,

day = "1",

doi = "10.1002/bkcs.10402",

language = "English",

volume = "36",

pages = "2179--2184",

journal = "Bulletin of the Korean Chemical Society",

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TY - JOUR

T1 - Quinoline-substituted zinc(II) phthalocyanine for the dual detection of ferric and zinc ions

AU - Gupta, Ankush

AU - Kim, A. Rong

AU - Kim, Kyung Sub

AU - Na, Kun

AU - Choi, Myung Seok

AU - Park, Jong S.

PY - 2015/9/1

Y1 - 2015/9/1

N2 - Here we present the synthesis and properties of quinoline-substituted zinc(II) phthalocyanine, Zn[Pc(O-QN)4]. Zn[Pc(O-QN)4] can function as a highly selective chemosensor against Fe3+ and Zn2+ ions, exhibiting efficient fluorescence quenching and enhancement, respectively. Various characterization techniques were employed to investigate the intermolecular interactions of Zn[Pc(O-QN)4] with metal ions. A double-electron exchange and a forbidden photoinduced electron transfer behavior in Zn[Pc(O-QN)4] were attributed to such opposite responses. Furthermore, by taking advantage of selectivity, we successfully employed Zn[Pc(O-QN)4] to stain and record confocal fluorescence microscopy images of Chang liver cells in the presence of metal ions.

AB - Here we present the synthesis and properties of quinoline-substituted zinc(II) phthalocyanine, Zn[Pc(O-QN)4]. Zn[Pc(O-QN)4] can function as a highly selective chemosensor against Fe3+ and Zn2+ ions, exhibiting efficient fluorescence quenching and enhancement, respectively. Various characterization techniques were employed to investigate the intermolecular interactions of Zn[Pc(O-QN)4] with metal ions. A double-electron exchange and a forbidden photoinduced electron transfer behavior in Zn[Pc(O-QN)4] were attributed to such opposite responses. Furthermore, by taking advantage of selectivity, we successfully employed Zn[Pc(O-QN)4] to stain and record confocal fluorescence microscopy images of Chang liver cells in the presence of metal ions.

KW - Dual detection

KW - Fluorescence quenching

KW - Phthalocyanine

KW - Quinolone-substituted

KW - Stern-Volmer constant

UR - https://www.scopus.com/pages/publications/84941599379

U2 - 10.1002/bkcs.10402

DO - 10.1002/bkcs.10402

M3 - Article

AN - SCOPUS:84941599379

SN - 0253-2964

VL - 36

SP - 2179

EP - 2184

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 9

ER -

Quinoline-substituted zinc(II) phthalocyanine for the dual detection of ferric and zinc ions

Abstract

Bibliographical note

Keywords

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